8th International Congress on Sustainability Science & Engineering (ICOSSE '19)

Modification of F-Doped TiO2 Nanorods with Rgo for Rhodamine B Photodegradation

Authors

Hidayat, R. - Presenter, Sebelas Maret University
Wahyuningsih, S., Faculty of Mathematics and Natural Sciences, Universitas Sebelas Maret
Ramelan, A. H., Electronic Materials and Energy Research Group, Universitas Sebelas Maret

TiO2-based combination materials have been developed to enhance photodegradation performance. The combination of structural engineering modifications of nanorods, F atoms doping and composites with rGO was able to eliminate the problems that occur in photocatalyst material. The structural engineering of nanorods increases the surface area of TiO2 so the interaction between dye molecules and photocatalyst also increases. Then, the presence of F atoms in the TiO2 crystal lattice caused defects that allow the red shift in the UV-Vis wavelength range. The absorption shift was known from the characterization of the UV-Vis spectrophotometer. The rGO material is able to avoid recombination rate that often occur in photocatalytic processes. This material has a high surface area and good electronic conductivity so that can capture electrons (e-) which are separate from holes (h+). The formation of TiO2-based combination materials was characterized by XRD, SAA, SEM and FTIR. Then, the photodegradation activity test was carried out on Rhodamine B with a time variation of 0, 30, 60, 90 and 240 minutes. The combination of modification of TiO2-based photocatalyst material was able to enhance photodegradation performance compared to TiO2 P25.