2025 Spring Meeting and 21st Global Congress on Process Safety
(41s) Replacement of HDS Reactor Due to Cracking Identification
Historically, there have been several notable incidents attributed to the HTAH process. One of the most significant accidents occurred at a refinery in the United States, where a failure in a hydrogen reactor led to a massive explosion. This incident resulted in significant injuries and extensive damage to the facility. Investigations revealed that the root cause was related to the degradation of materials used in the reactor, exacerbated by the harsh operating conditions of HTAH.
Another serious accident took place in Europe, where a leak in a high-pressure hydrogen line resulted in a fire. The investigation highlighted the lack of proper maintenance and monitoring systems, which allowed the leak to go undetected until it ignited. This incident underscores the importance of rigorous maintenance protocols and the regular inspection of equipment used in HTAH processes.
The risks associated with HTAH are not limited to catastrophic accidents; they also include long-term safety concerns related to material degradation. Hydrogen embrittlement, a phenomenon where metals become brittle due to hydrogen exposure, poses a significant threat to the integrity of equipment in HTAH environments. This has led to increased scrutiny and the implementation of more stringent safety regulations in the industry.
Replacement of HDS Reactor Due to Cracking Identification
The replacement of a Hydrodesulfurization (HDS) reactor is a critical operation necessitated by the identification of cracks in its structure, particularly in stages 2 and 3 of HTAH. When cracks are detected, especially at these advanced stages, it indicates significant material fatigue and potential failure risks.
The process of replacing an HDS reactor began with a thorough assessment of the existing reactor. Engineers conducted non-destructive testing (NDT) methods, such as ultrasonic testing or radiographic inspection, to evaluate the extent of cracking and the overall health of the reactor. Once the decision to replace the reactor is made, a detailed plan was developed to ensure the safe and efficient removal of the old reactor and installation of the new one.
During the replacement process, safety is paramount. The area around the reactor is secured, and all necessary precautions are taken to mitigate the risks associated with HTAH. This includes purging the reactor of any remaining hydrogen and ensuring proper ventilation.The process was carried out in a fully operational unit, which made the replacement of the reactor much more challenging.
The new HDS reactor is typically designed with improved materials and technology to withstand the harsh conditions of HTAH. Modern reactors often incorporate advanced alloys or coatings that offer better resistance to hydrogen embrittlement and other forms of degradation. Additionally, the design may include enhanced monitoring systems to detect potential issues before they escalate into serious problems.
For the replacement, a reactor from an existing unit under construction was used, which had sufficient time for the acquisition of new equipment, while the replacement of the existing operational unit would eliminate the present risk associated with the cracks identified in stages 2 and 3.