2016 AIChE Spring Meeting and 12th Global Congress on Process Safety
(63ab) Optimization of Layered Graphene Oxide Nanostructures through Controlling the Membrane Deposition Rate Towards Size-Sieving Separation
Single-layer graphene oxide (GO) flakes were coated on anodized aluminum oxide (AAO) substrate through a simple vacuum filtration process, the effect of the deposition rate on the nanostructures of obtained membrane was investigated though pure water flux and organic vapor diffusion, which indicated GO membrane assembled with slow deposition rate might have more ordered lamellar structure and, correspondingly, have smaller effective pore size. In contrast, under fast deposition rate, GO flakes assembled in a more random way. Therefore, through controlling the membrane deposition rate, the nanostructure of layered GO membrane could be optimized for size dependent separation. We found after thermal reduction, 100 nm GO membrane (prepared @ 0.02 nm/s) has effective pore size smaller than 6.1 Å, which exhibit great potential in n-hexane/2,2-dimethybutane (DMB) separation.