2012 Spring Meeting & 8th Global Congress on Process Safety
(28e) Mass Transfer Effects in Bore-Hole Filter-Cake Cleanup
Authors
Harwell, J. - Presenter, University of Oklahoma
Sabatini, D. - Presenter, University of Oklahoma
A microemulsion-based fluid designed for removal of bore-hole filter-cake removal was studied to determine the dominant mechanism of cake dissolution. Two distinct regimes were identified as a function of temperature and pressure. At low pressure calcium carbonate dissolution to release carbon dioxide created interfacial turbulence that dominated the interphase mass transfer to such an extent that carbonate dissolution rates predicted the cake break-up time. At increased pressure, however, carbon dioxide generation no longer correlated with the cake breakup time, and oil-solubilization, dominated by surfactant diffusion rates, became the rate determining step.