2012 Spring Meeting & 8th Global Congress on Process Safety
(139b) Fuel Processing for Hydrogen Production in Fuel Cell Applications
Author
High to ultra-high purity hydrogen may be needed for the durable and efficient
operation of fuel cells. Impurities are believed to cause various problems in the
current state-of-the-art fuel cell designs, including catalyst poisoning and membrane
failure. As such, additional process steps may be required to purify the hydrogen to
meet industry quality standards. Additional steps could also be needed if carbon
capture and sequestration technologies are developed and utilized as part of this
method of hydrogen production.
During the production of hydrogen, CO2 is also produced. The SMR process in centralized plants emits
more than twice the CO2 than hydrogen produced To avoid emission of CO2 into the atmosphere, CO2
can be concentrated, captured, and sequestered; sequestration concepts and technologies are relatively
new and there is no long-term test evidence to prove that these technologies will be successful.
Sequestration in oceans is controversial because of the possible adverse impact on the aquatic environment by the reduction of ocean water pH.
Steam reforming of natural gas is widely used in industry today. Hydrogen is
produced by the SMR process in large centralized industrial plants for use in
numerous applications, including chemical manufacturing and petroleum refining.
Research and development (R&D) programs are currently investigating the
development of small-scale SMR technologies to enable the development of smallscale, distributed hydrogen production and delivery infrastructure.