2008 Spring Meeting & 4th Global Congress on Process Safety

(220a) Top 5 Contaminants in Ethylene Production Unit Feedstocks

Authors

Brayden, M. - Presenter, The Dow Chemical Company
Hines, D. - Presenter, BASF Corporation
Graham, J. - Presenter, ExxonMobil Chemical Co.
Baumgartner, A. - Presenter, Shell Chemical Co.
Pickett, T. - Presenter, Shaw Stone & Webster Inc.


Trace contaminants in feedstocks to ethylene production units cause various processing issues and impact final product purity. This paper explores the top 5 feedstock contaminants that were identified in the 2004 survey paper, "Feedstock Contaminants in Ethylene Plants -- An Update". According to the survey, the top five contaminants, based on number of respondents reporting issues with it, are sulfur, methanol, sodium, chlorides, and carbon dioxide. Each impurity will be discussed in some detail as to the source of the contaminant, how it partitions in the plant, any reactions that it may undergo, how it is removed, analytical methods, and its impact on final product specifications.