2024 AIChE Annual Meeting

(535a) Large-Scale CO2 Utilization for Production of Methanol in Carbon-Intensive Jurisdictions

Authors

Jubil Joy, University of Alberta
Amit Kumar, University of Alberta
This study explores the potential of large-scale CO2 utilization to produce methanol in regions heavily reliant on carbon-intensive energy sources, such Alberta, a western province in Canada. There is an urgent need to mitigate carbon emissions and transition to cleaner energy alternatives. Thus, the main objective is to assess the techno-economic feasibility and environmental impact of using CO2 hydrogenation processes for methanol synthesis, with a focus on jurisdictions with substantial carbon footprints. The scope extends to evaluating the efficiency improvements, cost implications, and potential carbon reduction.

The methodology includes comprehensive process modeling. The models are developed to represent the methanol synthesis process through CO2 hydrogenation reactions, including different scenarios and operational parameters. CO2 is sourced from atmospheric air using direct air capture (DAC), a carbon removal technology. The study focuses on the large-scale production of methanol, 7,000 tonnes per day, via CO2 hydrogenation, and its comparison to methanol production via conventional natural gas-based technologies, steam methane reforming (SMR) and autothermal reforming (ATR). CO2 hydrogenation for methanol production includes DAC unit and hydrogen production. This research provides a detailed understanding of the methanol production process, identifies optimal operating conditions, and estimates the potential for carbon emission reduction. A sensitivity analysis is also included to understand the impact of variable feedstock prices, energy costs, and carbon pricing mechanisms on the overall feasibility of the process. The results provide a clear picture of the potential efficiency gains, cost benefits, and environmental impacts associated with hydrogen utilization in methanol production within carbon-intensive jurisdictions.

The study makes a novel contribution by providing region-specific insights and recommendations that would benefit jurisdictions with high carbon footprints. The comprehensive modeling approach and utilization of simulation model offers a robust foundation for evaluating the large-scale production of methanol. It ensures a thorough and accurate analysis, setting the basis for informed decision-making and sustainable industrial practices. The study focuses on establishing a clear link between CO2 utilization, economic viability, and carbon emission reduction, for the adoption of CO2 -based technologies in carbon-intensive regions.