2024 AIChE Annual Meeting

(498f) Optimization of CO2 Pipeline Networks for Climate Change Mitigation

Authors

Lastoskie, C. - Presenter, University of Michigan
Nathan, A., University of Michigan
Over the last century, the United States has invested in an extensive network of wastewater collection systems to remove pathogens, dissolved organic matter, and industrial effluents from municipal wastewater streams. The investment secured a thousand-fold decrease in waterborne diseases and dramatically reduced fouling of surface waters from eutrophication. A comparable, nation-spanning investment is now needed to meet ambitious goals for arresting global climate change: namely, investment in gaseous pollutant collection systems to transport CO2 recovered from major industrial sector greenhouse gas (GHG) emitters. Stabilizing the climate requires far more than electrifying automobile fleets and building wind and solar farms. Gigaton scale CO2 capture, utilization, and storage (CCUS) is needed to cost-effectively achieve deeply decarbonized systems, e.g. 80% GHG emission reductions by 20501, and negative emissions systems, crucial to meet 1.5 degrees Celsius warming limits. Existing pipeline infrastructure is inadequate in scale and location to transport captured CO2 from carbon-emitting heavy industries to geologic sinks and CO2-utilizing manufacturers2. Deployments of CO2 capture and pipeline facilities are challenged by high capital costs, weak policy incentives for capturing CO2, patchwork intra-state CO2 pipeline laws, and an absence of federal authority over interstate CO2 pipeline siting. Overcoming cost and pipeline siting regulatory constraints could significantly accelerate CCUS deployment.

Large industrial CO2 sources by sector include refineries (188 Mt CO2/yr), pulp and paper (143), iron and steel (83), petrochemicals (80), and cement (68). The CO2 content in the exhaust gases from these sources also varies widely, with high fractions in ammonia, ethanol, and petrochemical plants (30-99.9+%) and medium to low concentrations from cement (14-33%), iron and steel (20-27%), and pulp and paper (8%) manufacturing3. The work requirement and the corresponding cost to separate CO2 from the exhaust at purity suitable for pipeline transport varies in inverse proportion to the CO2 content of the exhaust, ranging up to $70/ton CO2 for capture from low concentration sources (e.g., natural gas power plants) using current state-of-art amine solvent capture technologies.

A sequential strategy is thus indicated for scaling industrial sector CCUS, with inexpensive near-term capture from industrial facilities that emit exhaust with high CO2 content, followed by the addition of CO2 from sources with progressively lower exhaust CO2 concentrations, allowing time for the maturation of technology alternatives to amine scrubbing that may enable lower-cost CO2 separation from dilute gas streams. Tandem to the sourcing considerations is the sale value of the captured CO2 at its utilization site (or, in the case of carbon sequestration, the additional cost of CO2 injection into a storage reservoir), as well as tariffs assessed to pipeline users for compression and transport of captured CO2 from its industrial source to its intended endpoint. Presently the scale of CO2 utilization is only 1% of total emissions, mostly for EOR operations in west Texas using CO2 that is pipelined from natural underground reservoirs in New Mexico. Additional EOR operations, as well as expanded CO2 utilization in other industries, are thought to be viable if CO2 from anthropogenic sources is available for purchase at the typical oil-linked price of 40% of the per-barrel oil price per ton of CO2. Investment in CO2-dedicated pipeline infrastructure, financed in part or in whole by the government, can thus accelerate CCUS adoption to scales sufficient to alter the planet’s climate change trajectory by removing the “chicken-or-egg” barrier of linking large-scale CO2 emission sources to CO2 utilization or storage sinks.

In this presentation, we report on a methodology that was developed to optimize the sequential construction of CO2 capture facilities and pipeline networks, to convey CO2 from hard-to-decarbonize industrial processes to sites for CO2 utilization as a feedstock. Capture costs and available CO2 flow volumes from regional industrial emission sources in the Atlantic, Pacific, Midwest, and Southeastern U.S. were compiled from EPA datasets. Placement of trunk pipeline segments for aggregated CO2 flows, within existing rights of way (e.g., corridors for natural gas pipelines, electricity transmission lines, interstate highways) was then determined using ArcGIS, and pipe diameters, lengths, and costs to build and operate pipeline networks connecting CO2 sources to the trunk lines were calculated. Financial analysis was next conducted to determine the economic viability of pipeline networks of varying spatial extent and installation timetables under financing scenarios with partial and full government backing, taking into account pipeline tariffs, oil-linked CO2 sale prices, availability of Section 45Q carbon sequestration credits, equity target internal rate of return, and technology advancements leading to lower future CO2 capture costs.

A crucial systems interdependency of the CO2 pipeline network is that the shared cost per unit flow in the pipeline increases as the flow volume decreases. The cost of CCUS abatement for one pipeline user is therefore dependent on the costs incurred by all other users on the same network, and whether or not those other prospective CO2 “sellers” elect to use the pipeline system to bring their own CO2 to market. The pipeline network is thus an inherently dynamic system, such that the financial analysis of the sized networks must be carried out iteratively until an economically viable network design is attained.

A case study is presented for the construction and operation of dedicated CO2 pipeline network for the transport and delivery of captured carbon dioxide from industrial emitters along the Eastern seaboard of the United States to a terminal in Louisiana for enhanced oil recovery operations. Pipeline funding scenarios that involve full commercial financing, full government financing, and private-public partnership were investigated with the use of the Department of Energy's FE/NETL CO2 Transport Cost Model. The range of capacity additions that are possible, beyond a baseline of 68 Mt CO2/yr for full government financing of the pipeline, were explored for different technology advancement scenarios leading to a decrease in future onsite CO2 capture costs.

  1. Sustainable Development Solutions Network and the Institute for Sustainable Development and International Relations. Pathways to deep decarbonization. Deep Decarbonization Pathways Project (2015).
  2. National Energy Technology Laboratory and the Great Plains Institute. Siting and Regulating Carbon Capture, Utilization and Storage Infrastructure. U.S. Department of Energy Workshop Report (2017).
  3. P.C. Psarras, S. Comello, P. Bains, P. Charoensawadpong, S. Reichelstein, and J. Wilcox. Carbon Capture and Utilization in the Industrial Sector. Environmental Science and Technology (2017) 51, 11440-11449.