Recently, the Consortium for Waste Circularity has advocated the use of “Regenerative Robust Gasification” to simplify waste collection and boost recycling rates. Robust Gasification refers to a type of gasifier that can accept everything in municipal solid waste (MSW) without the need for sorting. It promises to convert unsorted municipal waste, including multi-layer plastics, metallized flexible films, and many materials that are not conducive to traditional recycling, into synthesis gas (syngas). Since syngas is not easily transported, the conversion of syngas into a fungible, widely used chemical feedstock is proposed. As the backbone of C1 chemistry, methanol is an ideal target. Unlike the gas-phase methanol production widely used in industry, alcohol-assisted syngas to methanol process has different reaction mechanism, requires lower reaction temperature, therefore providing a new possible path.