2021 Annual Meeting

(46b) A Mechanical Theory of Nonequilibrium Phase Coexistence and Its Application to Motility-Induced Phase Separation

Authors

Hyeongjoo Row - Presenter, California Institute of Technology
John Brady, California Inst of Technology
We present a mechanical theory of phase coexistence broadly applicable to nonequilibrium and equilibrium systems. Our approach is motivated by ideas developed nearly a half-century ago to study the behavior of inhomogeneous classical fluids. We demonstrate the utility of our method by applying it to the important problem of motility-induced phase separation (MIPS) of active Brownian particles. In addition to quantitatively determining the phase diagram of the MIPS in two and three dimensions, our theory predicts previously unreported anomalous interfacial phenomena, which we confirm by computer simulations. The self-consistent determination of bulk and interfacial phase behavior offered by this mechanical perspective provides a concrete path towards a general theory for nonequilibrium phase transitions.