2020 Virtual AIChE Annual Meeting
(191d) Atomically Thin Graphene Membranes with Nanoscale Pores for Dialysis Based Separations
Author
Kidambi, P. - Presenter, Vanderbilt University
Atomically thin membranes from 2D materials offer unique opportunities for molecular separations with high permeance and high selectivity. Here, we report the fabrication of fully functional centimeter scale nanoporous (<2-3nm) atomically thin graphene membranes for molecular separation applications. Our work focuses on systematically addressing key challenges that have limited progress in field i.e. a) scalable nanopore formation methods including in-situ approaches, b) facile support casting, c) novel defect sealing methods and d) scalable manufacturing approaches. The synthesized nanoporous atomically thin membranes show higher selectivity and permeance (up to 100 times more) than state-of-the-art polymeric membranes and can be readily used for lab-scale dialysis.
Cheng P. et al. Nat. Nano. (submitted)
Kidambi P.R. et al. Adv. Mat. 2018
Prozorovska L. and Kidambi P.R. Adv. Mat. 2018
Kidambi P.R. et al. ACS App. Mat. & Int. 2017
Kidambi P.R. et al. Adv. Mat. 2017
Kidambi P.R. et al. Adv. Mat. 2017
Kidambi P.R. et al. Nanoscale 2017