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- 2018 AIChE Annual Meeting
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- Directed and Self Assembly of Colloids
- (276g) Strain Fields in Repulsive Colloidal Crystals
This work explores the behavior of elastic moduli and strain fields around dislocations within simulated colloidal crystals interacting through a family of repulsive potentials with varying steepness. For steeper potentials, it is found that free energies of deformation are more dominated by entropy, tension-compression asymmetry near dislocation core increases, and the strain range of linear elastic applicability shrinks. We show that pressure is a key parameter for expanding the window of linear elastic applicability for very steep potentials. Using these insights, we show under what conditions linear elasticity theory can be used as a predicative tool in exploring defect-defect interactions in colloidal crystals.