Scale up Batch Reaction of Precision Polymers

ABSTRACT:

Morphologies of free radical polymers are difficult to study
due to the imprecise nature of the polymerization.  Acyclic Diene Metathesis, (ADMET) creates
strictly linear, and precisely spaced functional polymers from a variety of
different types of α, ω-diene monomers ^[1].   These polymers have demonstrated unique
morphologies and properties that are not readily available from other
polymerization techniques.  We have
performed ADMET polymerization on 1, 9 decadiene with the intent to scale the
polymerization, in order to determine whether this method is feasible for
commercial scale.  One of the major draw
backs of ADMET is the need for high vacuum techniques; this limits the use of
solvents to ionic liquids or other expensive, high boiling solvents.  Bulk conditions lead to high viscosity, poor
catalyst activity, difficult processability, and slower reaction times ^[2].   To this end we are exploring the use of high
boiling, commercially available and inexpensive solvents such as propylene carbonate
for ADMET polymerization.  From our
experiments, we have achieved a M_n≈9,600, which results in an X_n of 70 and overall conversion of 98.6%. 

Figure 1 illustrates the reaction mechanism of the described ADMET polymerization.

References:

[1] Baughman, Travis W., and
Kenneth B. Wagener. "Recent Advances in ADMET
Polymerization." Springer Berlin Heidelberg, 03
Feb. 2005.Print.

[2] Simocko, Chester, Yong Yang,
Timothy M. Swager, and Kenneth B. Wagener. "Metathesis Step-Growth Polymerizations in Ionic Liquid."
ACS Macro Lett. ACS Macro Letters 2.12
(2013): 1061-064. Web. 10 Oct. 2015.