2015 AIChE Annual Meeting Proceedings

(351b) The Molecular Nature of the Cu Active Sites Under NOx Selective Catalytic Reduction

Authors

Hui Li - Presenter, University of Notre Dame
Christopher Paolucci - Presenter, University of Notre Dame
Rajamani Gounder - Presenter, Purdue University
Atish A. Parekh - Presenter, Purdue University
Ishant Khurana - Presenter, Purdue University
John R. Di Iorio - Presenter, Purdue University
Arthur Shih - Presenter, Purdue University
Fabio H. Ribeiro - Presenter, Purdue University
W.N. Delgass - Presenter, Purdue University
William Schneider - Presenter, University of Notre Dame

The Molecular Nature of the Cu Active Sites Under NOx
Selective Catalytic Reduction

The selective catalytic reduction
(SCR) of NOx in excess oxygen is a key challenge
in meeting increasingly stringent emission regulations. The metal-exchanged
zeolite Cu-SSZ-13 in particular exhibits sufficient activity and hydrothermal
stability for practical applications. 
A primary obstacle for further
improvement of SCR catalysts is a lack of molecular-level understanding of the
active sites and mechanism.  Previous
work [1] identified isolated Cu ions in the six-membered ring of Cu-SSZ-13 as an
active site for the standard NH3-SCR reaction:

4 NH3 + 4
NO + O2 
→4 N2 + 6 H2O

Here, using density functional
theory (DFT) calculations, ab-initio
molecular dynamics (AIMD), and ab-initio thermodynamic
modeling we:

  1. Identify two forms of single Cu species, [Cu]2+ and [CuOH]+ as the precursors to the active Cu sites under SCR.  We show there is a strong thermodynamic driving force to preferentially form [Cu]2+ over [CuOH]+  and predict the resulting Cu speciation between the two as a function of the zeolite's Silicon to Aluminum (Si:Al) and Copper to Aluminum (Cu:Al) composition.

  1. Predict the response and resulting molecular structures of these different species to non-catalytic treatments including exposure to atmosphere at 298 K and oxidizing/reducing environments at 673 K.  We validate these molecular level predictions with X-Ray Absorption Spectroscopy (XAS) experiments.
  2. Identify the coordination these Cu species take under SCR and compare with operando XAS.  We then produce, and evaluate using DFT, a mechanism consistent with the previous results for SCR at 473 K on both sites.

We show that SCR occurs through a
redox mechanism at all isolated Cu sites regardless of their speciation, and
identify key reaction steps in the reduction and oxidation half cycles [2].  We then extend these ideas to other zeolite
supports.

References

1.    
Bates, S.A.,
Verma, A.A., Paolucci, C., Parekh, A.A., Anggara, T.,
Yezerets, A., Schneider, W.F., Miller, J.T., Delgass, W.N., and Ribeiro, F.H.,
J. Catal. 312,
87 (2014)

2.    
Paolucci, C.,
Verma, A.A., Bates, S.A., Kispersky, V.F., Miller,
J.T., Gounder, R., Delgass,
W.N., Ribeiro, F.H., and Schneider, W.F., Angew. Chem. Int. Ed. 53, 44 (2014)