2014 AIChE Annual Meeting
(352b) Kinetic Modeling of Hydrothermal Liquefaction of Algal Biomass
Authors
Harvind Kumar Reddy - Presenter, New Mexico State University
Tapaswy Muppaneni, New Mexico State University
Sundaravadivelnathan Ponnusamy, New Mexico State University
Thinesh Selvaratnam, New Mexico State University
Barry Dungan, New Mexico State university
Nagamany Nirmalakhandan, New Mexico State University
Tanner Schaub, New Mexico State University
Francisco Holguin, New Mexico State university
Peter Lammers, New Mexico State University
Wayne Voorhies, New Mexico State university
Shuguang Deng, New Mexico State University
A kinetic model for hydrothermal liquefaction (HTL) of algal biomass is proposed to predict the product distribution. This model is developed based on the experimental results obtained from a batch reactor. The experiments were conducted to study the effects of variations in biochemical composition of algal biomass produced at different time points of a heterotrophically grown culture under photosynthesis adaptation. The developed model is validated with the HTL experimental results available in literature. Along with the model development, the product distribution behavior is also studied at different experimental conditions. A micro bomb calorimeter is used to determine the high heating value (HHV) of the biocrude oil and bio-char. The biocrude oils and water soluble organic compounds were characterized with the High-Throughput Time of Flight Mass Spectrometer (HT TOF-MS) and GC-MS. Various analytical methods are used to study the behavior of lipids, proteins, amino acids, carbohydrates and other water soluble compounds.