2013 AIChE Annual Meeting

(589g) Model Reformulation for Lithium-Ion Battery Simulation and Control

Authors

Northrop, P. W. C. - Presenter, Washington University in St. Louis
Suthar, B., Washington University in St. Louis
Ramani, V., Washington University in St. Louis



A simple transformation of coordinates is proposed that facilitates the efficient simulation of the non-isothermal lithium-ion pseudo 2-D (P2D) battery model. [1-5] The transformed model is then conveniently discretized using orthogonal collocation with the collocation points in the spatial direction. The resulting system of differential algebraic equations (DAEs) is solved using efficient adaptive solvers in time. A series of mathematical operations are performed to reformulate the model to enhance computational efficiency as well as for programming convenience.[3] This is done to maintain accuracy even when non-linear temperature dependent parameters are used. Additionally, this methodology can be applied to the model as more physical phenomena, and therefore greater computational complexity and increased nonlinearities, are considered. The transformed coordinate allows for efficient simulation and allows for a logical extension from a single cell sandwich to multi-cell stack models. In order to demonstrate this, the transformation and reformulation techniques are used to simulate operation of a multi cell battery stack subject to varying heat transfer coefficients as well as specified temperature boundary conditions.

A strong physics based battery model can play a significant role in the model based design of battery architecture and optimal control of batteries for improved performance. [6] However, the computational cost of high level models has limited the utility of the same in many applications, driving the development of various mathematical techniques to reduce the computational requirements. [7-11] Improved computational efficiency of the reformulated models is essential to increase the viability of using such models in environments of limited computing power. This is implemented into model based Battery Management System (BMS) for vehicular applications with the aim to improve usable capacity and performance while maintaining safety. This talk will review the recent developments in efficient simulation of battery models, and in particular the improvements in the algorithms for inverse calculations encountered in state estimation, parameter estimation and model predictive control.

Acknowledgements – The authors are thankful for the financial support by the United States Government, Advanced Research Projects Agency – Energy (ARPA-E), US Department of Energy under award # DE-AR0000275, McDonnell Academy Global Energy and Environment Partnership (MAGEEP) at Washington University in St. Louis.

 References:

1.            Doyle, M., T.F. Fuller, and J. Newman, Modeling of Galvanostatic Charge and Discharge of the Lithium Polymer Insertion Cell. Journal of the Electrochemical Society, 1993. 140(6): p. 1526-1533.

2.            Doyle, M., et al., Comparison of modeling predictions with experimental data from plastic lithium ion cells. Journal of the Electrochemical Society, 1996. 143(6): p. 1890-1903.

3.            Northrop, P.W.C., et al., Coordinate Transformation, Orthogonal Collocation, Model Reformulation and Simulation of Electrochemical-Thermal Behavior of Lithium-Ion Battery Stacks. Journal of the Electrochemical Society, 2011. 158(12): p. A1461-A1477.

4.            Villadsen, J. and M.L. Michelsen, Solution of differential equation models by polynomial approximation1978: Prentice-Hall.

5.            Carey, G.F. and B.A. Finlayson, Orthogonal Collocation on Finite-Elements. Chemical Engineering Science, 1975. 30(5-6): p. 587-596.

6.            Ramadesigan, V., et al., Modeling and Simulation of Lithium-Ion Batteries from a Systems Engineering Perspective. Journal of the Electrochemical Society, 2012. 159(3): p. R31-R45.

7.            Cai, L. and R.E. White, Reduction of Model Order Based on Proper Orthogonal Decomposition for Lithium-Ion Battery Simulations. Journal of the Electrochemical Society, 2009. 156(3): p. A154-A161.

8.            Klein, R., et al. State estimation of a reduced electrochemical model of a lithium-ion battery. in Proceedings of the American Control Conference. 2010.

9.            Smith, K.A., C.D. Rahn, and C.Y. Wang, Control oriented ID electrochemical model of lithium ion battery. Energy Conversion and Management, 2007. 48(9): p. 2565-2578.

10.          Subramanian, V.R., et al., Mathematical Model Reformulation for Lithium-Ion Battery Simulations: Galvanostatic Boundary Conditions. Journal of the Electrochemical Society, 2009. 156(4): p. A260-A271.

11.          Forman, J.C., et al., Reduction of an Electrochemistry-Based Li-Ion Battery Model via Quasi-Linearization and Pade Approximation. Journal of the Electrochemical Society, 2011. 158(2): p. A93-A101.