2006 AIChE Annual Meeting
(256c) Dynamics and Collapses of Colloidal Lattices at Oil - Water Interfaces
Authors
Dai, L. L. - Presenter, Texas Tech University
Tarimala, S., Texas Tech University
Wu, C. Y., Texas Tech University
One interesting aspect of colloidal particles is the formation of colloidal crystals at the two-dimensional and three-dimensional level. Here we report the dynamics and collapses of ordered colloidal lattices at liquid-liquid interfaces using Pickering emulsions as an experimental template. The colloidal particles oscillate around their equilibrium positions. The short-time diffusion constant of single particles increases with increasing the lattice spacing; the oil phase viscosity only has an effect on diffusion at large inter-particle distances. Strikingly, we observe that the ordered equilibrium structure can be disturbed when increasing the output laser intensity in a confocal laser scanning microscope which leads to the collapse of colloidal lattices under small radiation pressure forces.