2006 AIChE Annual Meeting
(164j) Europium Doped Yttrium Oxide Nanoparticle-Silica Composite as an Energy-Efficient Phosphor Material
Authors
Kim, J. N. - Presenter, Korea Institute of Energy Research
Ko, C. H., Korea Institute of Energy Research
Song, H. I., Korea Institute of Energy Research
Park, J. H., Korea Institute of Energy Research
Han, S. S., Korea Institute of Energy Research
Beum, H. T., Korea Institute of Energy Research
Europium doped yttrium oxide (Y2O3:Eu) has been one of the most effective phosphors for red light. To enhance the efficiency of Y2O3:Eu further more, many researchers have tried to synthesize round type, non-porous Y2O3:Eu particles with uniform size. Flame pyrolysis and solution phase colloidal synthesis have been the major methods to synthesize energy-efficient nanosize Y2O3:Eu phosphors. In this presentation, we developed a new method to synthesize energy-efficient Y2O3:Eu by combination of Y2O3:Eu with silica. Y2O3:Eu nanoparticle-silica composite materials was synthesized by the impregnation of yttrium and europium precursors inside the pores of mesoporous silica. Thermal treatment at 823 K in oxygen atmosphere converted metal precursors into Y2O3:Eu particles. The measurement of high-resolution transmission electron microscopy and x-ray diffraction pattern confirmed that Y2O3:Eu nanoparticles were incorporated inside the pores of mesoporous silica. Photoluminescence study showed that the efficiency of Y2O3:Eu nanoparticle-silica composite for red light emitting was much higher than that of bulk Y2O3:Eu, which was synthesized with the same treatment method without mesoporous template.